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1 article(s) from Roke, Diederik

A chiral self-sorting photoresponsive coordination cage based on overcrowded alkenes

Constantin Stuckhardt,
Diederik Roke,
Wojciech Danowski,
Edwin Otten,
Sander J. Wezenberg and
Ben L. Feringa

Beilstein J. Org. Chem. 2019, 15, 2767–2773, doi:10.3762/bjoc.15.268

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Graphical Abstract

Figure 1: Schematic representation of a photoresponsive cage with ligands based on overcrowded alkenes.

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Scheme 1: Cage formation of overcrowded alkene switches E/Z-1 and their isomerization behavior. Note that the...

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Figure 2: Aromatic region of stacked ¹H NMR spectra (in CD₃CN) of stable Z-1 and cage complex Pd₂(stable Z-1)₄...

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Figure 3: HRMS spectra of cage complex Pd₂(stable Z-1)₄ (top) and cage complex Pd₂(stable E-1)₄ (bottom); Ins...

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Figure 4: Crystal structure of cage complex Pd₂(stable E-1)₄ (top left) and DFT optimized structures of cage ...

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Figure 5: Aromatic region of stacked ¹H NMR spectra (CD₃CN/CD₂Cl₂ 1:1) of i) Pd₂(stable Z-1)₄; ii) Pd₂(stable ...

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Published 15 Nov 2019

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